Plotting Maucha Diagram based on Matlab and its applications on hydrochemistry

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  • 1Taiyuan Normal University,School of Geographical Sciences,Jinzhong 030619,Shanxi,China; 2The construction and management station of three North Shelterbelt Project in Baiyin,Baiyin 730900,Gansu,China

Received date: 2019-01-28

  Revised date: 2019-04-29

  Online published: 2019-09-19

Abstract

The content and the proportion of soluble ions in water are important indicators to assess water quality,but common methods used in hydrochemistry cannot reflect the two relationships simultaneously.Maucha diagram not only reflects the total concentration of eight main anions and cations in water(i.e.CO32-,HCO3-,Cl-,SO42-,Mg2+,Ca2+,Na+ and K+),but also indicates relative and absolute concentrations for each ion simultaneously.Thus,the Maucha diagram is deemed to be very practical.However,due to the lack of professional software to plot Maucha diagram,the application of this diagram is very limited in hydrochemical research.In this paper,firstly,we introduced the evolution history of Maucha diagram which was proposed by Maucha in 1932 and developed by Hedgpeth and BROCH.Secondly,we introduced the components of Maucha diagram and its implications.This diagram makes up of a circle and eight quadrangles inside.The area of the tangent 16-sided polygon in the circle is utilized to represent the total concentration of eight anions and cations,and the area of the eight quadrangles represents the content of eight ions.In addition,the total cations and anions are supposed to submit the charge balance principle and the mass balance principle.Thirdly,the methods of how to establish a coordinate system and determine the coordinates of the circle and quadrangles in Maucha diagram were introduced in detail.Fourthly,the program flow of how to plot Maucha diagram based on Matlab was stated.Finally,taking the eastern Hunshandake Sandy Land in Inner Mongolia,China as an example,this paper illustrated the applications of Maucha diagram in the field of hydrochemical analysis for natural waters.The Hunshandake Sandy Land belongs to a climate transition zone near the middle-latitude boundary of semi-humid and semi-arid to arid climate.Elevations in Hunshandake Sandy Land decrease from ca.1 300 m in the southeast to ca.1 000 m a.s.l.in the northwest,while mean annual precipitation decreasing from ~450 mm in the southeast to 150 mm or so in the northwest.Since natural water in Hunshandake Sandy Land is characteristic of high concentration of NO3-and very low concentration of CO32-,we used NO3- instead of CO32- to plot Maucha diagram with Matlab.Before plotted Maucha diagram,we checked the ion data and only charge balance and mass balance data were used.Applications show that Maucha diagram has strong advantages in reflecting the total concentration of anions and cations,indicating the relative and absolute concentrations ions,judging the hydrochemical type of water body and spatial analysis for hydrochemical data.Compared to other computer languages,the Maucha diagram program written by Matlab can run on almost all kinds of computer systems,and have better readability and visualization.Moreover,based on hydrochemical characteristics of certain study area,the program can be developed to adapt to new situations,such as in this paper we use NO3- rather than CO32- to plot Maucha diagram.Thus,the application of the diagram may improve the visual expression ability for hydrochemical data,enrich the application of diagrams in hydrochemistry,and provide a reference for further analysis of hydrochemical data.

Cite this article

REN Xiao-zong, LIU Min, LI Jian-gang, LI Ji-yan .

Plotting Maucha Diagram based on Matlab and its applications on hydrochemistry[J]. Arid Land Geography, 2019 , 42(5) : 1069 -1077 . DOI: 10.12118/j.issn.1000-6060.2019.05.13

References

[1]夏军,翟金良,占车生.我国水资源研究与发展的若干思考[J].地球科学进展,2011,26(9):905-915.[ XIA Jun,ZHAI Jinliang,ZHAN Chesheng.Some reflections on the research and of development water resources in China[J].Advances in Earth Science,2011,26(9):905-915.] [2]周迪,周丰年,钟绍军.我国人均水资源量分布的俱乐部趋同研究——基于扩展的马尔科夫链模型[J].干旱区地理,2018,41(4):867-873.[ZHOU Di,ZHOU Fengnian,ZHONG Shaojun.“Club convergence”of per capita water resource distribution in China:Based on extended Markov chain model[J].Arid Land Geography,2018,41(4):867-873.] [3]李锋瑞,刘七军,李光棣.水资源管理模式评述与展望[J].中国沙漠,2008,28(6):1174-1179.[LI Fengrui,LIU Qijun,LI Guangdi.Patterns of water resources management:Overviews and prospects[J].Journal of Desert Research,2018,41(4):867-873.] [4]韩知明,贾克力,史小红,等.克鲁伦河流域下游水体氢氧同位素与水化学特征[J].干旱区地理,2019,42(1):85-93.[HAN Zhiming,JIA Keli,SHI Xiaohong,et al.Hydrochemical and hydrogen and oxygen isotopic characteristics of water in the low reach of Kherlen River[J].Arid Land Geography,2019,42(1):85-93.] [5]王利杰,曾辰,王冠星,等.西藏山南地区沉错湖泊与径流水化学特征及主控因素初探[J].干旱区地理,2017,40(4):737-745.[WANG Lijie,ZENG Chen,WANG Guanxing,et al.Chemical characteristics and impact factors of the Drem-tso Lake and supplying runoff in the Southern Tibet[J].Arid Land Geography,2017,40(4):737-745.] [6]文广超,王文科,段磊,等.基于水化学和稳定同位素定量评价巴音河流域地表水与地下水转化关系[J].干旱区地理,2018,41(4):734-743.[WEN Guangchao,WANG Wenke,DUAN Lei,et al.Quantitatively evaluating exchanging relationship between river water and groundwater in Bayin River Basin of Northwest China using hydrochemistry and stable isotope[J].Arid Land Geography,2018,41(4):734-743.] [7]MAUCHA R.Hydrochemische methoden in der limnologie[J].Binnengewasser,1932,12:173. [8]HEDGPETH J W.Some preliminary considerations of the biology of inland mineral waters[J].Arch Oceanog Limnol,1959,11(Suppl.):111-141. [9]BROCH E S.A modification of Maucha’s ionic diagram to include ionic concentrations[J].Limnology and Oceanography,1969,14:933-935. [10]HASSELL A,MARTIN D F.A computer-generated(q-basic) program to construct maucha diagrams[J].Florida Scientist,1995,58(3):300-254. [11]任孝宗,刘敏,张迎珍,等.基于Matlab的Durov三线图的实现[J].干旱区地理,2018,41(4):744-750.[REN Xiaozong,LIU Min,ZHANG Yingzhen,et al.Plotting Durov Diagram based on Matlab[J].Arid Land Geography,2018,41(4):744-750.] [12]APPELO A,POSTMA D.Geochemistry,groundwater and pollution[M].2nd ed.Amsterdam:Taylor & Francis,2005. [13]HAROLD V,SILBERBAUER M,MALULEKE M.Geographical differences in the relationship between total dissolved solids and electrical conductivity in South African Rivers[J].Water SA,2014,40(1):133-138. [14]CONZONNO V H,ULIBARRENA J.Hydrochemistry of lakes of the Patagonian Province of Tierra del Fuego(Argentina) [J].Environmental Earth Sciences,2010,59(7):1431-1436. [15]REN X,ZHU B,LIU M,et al.Mechanism of groundwater recharge in the middlelatitude desert of Eastern Hunshandake,China:diffuse or focused recharge[J]? Hydrogeology Journal,2018,27(2):761-783. [16]靳鹤龄,苏志珠,孙良英,等.浑善达克沙地全新世气候变化[J].科学通报,2004,49(15):1532-1536.[JIN Heling,SU Zhizhu,SUN Liangying,et al.Climate change in Holocene,Hunshandake Sandy Land[J].Chinese Science Bulletin,2004,49(15):1532-1536.] [17]张洪,靳鹤龄,苏志珠,等.全新世浑善达克沙地粒度旋回及其反映的气候变化[J].中国沙漠,2005,25(1):1-7.[ZHANG Hong,JIN Heling,SU Zhizhu,et al.Climate changes revealed by grain-size cycles of Holocene in Hunshandake Desert[J].Journal of Desert Research,2005,25(1):1-7.] [18]YANG X,LI H,CONACHER A.Large-scale controls on the development of sand seas in Northern China[J].Quaternary International,2012,250(2012):74-83. [19]朱震达,吴正,刘恕,等.中国沙漠概论[M].北京:科学出版社,1980.[ZHU Zhenda,WU Zheng,LIU Shu,et al.An Outline of Chinese Deserts[M].Beijing:Science Press,1980.] [20]YANG X,ZHU B,WANG X,et al.Late Quaternary environmental changes and organic carbon density in the Hunshandake Sandy Land,Eastern Inner Mongolia,China[J].Global and Planetary Change,2008,61(1-2):70-78. [21]YANG X,WILLIAMS M J.The ion chemistry of lakes and late Holocene desiccation in the Badain Jaran Desert,Inner Mongolia,China[J].Catena,2003,51(1):45-60. [22]吴月,王乃昂,赵力强,等.巴丹吉林沙漠诺尔图湖泊水化学特征与补给来源[J].科学通报,2014,59(12):1140-1147.[WU Yue,WANG Nai’ang,ZHAO Liqiang,et al.Hydrochemical characteristics and recharge sources of Lake Nuoertu in the Badain Jaran Desert[J].Chinese Science Bulletin,59(12):1140-1147.] [23]陈立,王乃昂,王浩,等.巴丹吉林沙漠湖泊与地下水化学参数初步研究[J].中国沙漠,2012,32(2):531-538.[CHEN Li,WANG Nai’ang,WANG Hao,et al.Spatial patterns of chemical parameters of lakes and groundwater in Badain Jaran Desert[J].Journal of Desert Research,2012,32(2):531-538.] [24]朱秉启,杨小平.塔克拉玛干沙漠天然水体的化学特征及其成因[J].科学通报,2007,52(13):1561-1566.[ZHU Binqi,YANG Xiaoping.Chemical composition of natural waters and its origin in the Taklamakan Desert[J].Chinese Science Bulletin,2007,52(13):1561-1566.]
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